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In 2001, WHA International, Inc. investigated a major industrial oxygen fire that resulted in significant damage as well as personnel injury and one death. The fire was initiated in a 6 in. (150 mm) ball valve while it was being opened under a low pressure differential, which caused extensive burnout. The results of this incident emphasize the extreme nature of fires in oxygen pipeline systems and underscore several important considerations in the design and operation of these systems.
During July of 2001 a fire occurred in a 6 in. (150 mm) ball valve being used as an oxygen pipeline isolation valve (shown here).
Just prior to the fire, the valve had been closed and a leak check was performed on the valve by bleeding off pressure downstream and monitoring the pressure differential across the valve. During this leak check, system data indicated that the upstream pressure was approximately 550 psig (3.8 MPa) and the downstream pressure was approximately 510 psig (3.5 MPa), or roughly a 40-psig (0.28 MPa) differential pressure.
At this point, the valve was to be re-opened to establish flow and provide full system pressure. As the valve was being opened manually by the hand wheel, ignition and fire developed within the valve that consumed most of the valve internals and surrounding valve body, as well as downstream piping and flanges. Tragically, the operator was killed in the incident.
WHA International, Inc was contacted to provide forensic investigation and failure analysis of the incident. WHA’s unique industry experience and expertise were exactly what the client needed to determine the origin and cause of the fire. Thorough understanding of the accident was critical to preventing such a tragic incident from occurring again.
WHA’s approach to investigating oxygen fires is detailed and thorough. Our engineers apply the concepts from international standards that they themselves helped develop, including ASTM G 88 (Standard Guide for Designing Systems for Oxygen Service), G 63 (Standard Guide for Evaluating Nonmetallic Materials for Oxygen Service), G94 (Standard Guide for Evaluating Metals for Oxygen Service) and G-145 (Standard Guide for Studying Fire Incidents in Oxygen System).
WHA’s forensic engineers first began by documenting and reconstructing the available evidence and examining a similar “exemplar” valve that was also installed in the same oxygen system. This undamaged exemplar valve proved useful to the investigation in many ways, providing a reference for the valve’s actuator positioning and samples of materials, especially lubricants, which had largely been consumed in the incident valve. The exemplar valve was referenced, along with the use of other analytical tools, to reconstruct the burned fragments into their approximate original positions and to create a three dimensional model of the valve’s internal flow passages.
The incident reconstruction provided three major insights:
The fire damage and melt/flow patterns discussed above suggested that ignition took place within the upstream seat retainer, which contained a wave spring packed with a lubricating grease as supplied through two grease-injection ports in the valve body. Samples of this lubricating grease were taken from the exemplar valve and analyzed to be consistent with a heavy hydrocarbon grease, which is highly flammable and easy to ignite in oxygen. This same lubricant is believed to have also been within the incident valve at the time of the fire. This evidence suggested that contaminant promoted ignition could have occurred while the valve was opening due to the mechanical energy created by the pressure differential causing high-frequency movement of the contaminated wave springs and the re-establishment of flow through the valve.
However, conditions at the time of the fire gave credibility to another potential ignition source as well. Though the valve was being opened with a low differential pressure, initial calculations using standard isentropic flow equations for compressible fluids estimated the gas velocities through the valve to be sufficient to potentially ignite particles. Because of this, WHA engineers also considered particle impact ignition as a possible ignition source.
To further evaluate the most probable ignition scenario and associate the observed melt/flow patterns, a 3D model of the valve was developed to approximate the geometric relationships of the valve internals and perform computational fluid dynamics (CFD) modeling of the flow conditions believed to be present in the valve at the time of the fire. Of specific interest were gas velocities and vector streamlines, as well as pressure and temperature conditions throughout the valve. The WHA CFD analysis predicted that the gas velocity would have exceeded 300 ft/s (90 m/s) immediately downstream of the valve’s seat, both where the flow entered the ball’s interstage (upstream) and where flow exited the interstage (downstream). The CFD analysis also predicted very turbulent flow downstream of the valve.
The characteristic elements for particle impact ignition include the presence of particles, high gas velocities, impingement locations, and flammable materials. Test data has shown that gas velocities greater than approximately 150 ft/s (45 m/s) are capable of supporting particle ignition in oxygen. Further, design guides for oxygen systems recommend limiting gas velocities to below 100 ft/s (30 m/s) to minimize particle impact ignition. The CFD analysis predicted that flow velocities in excess of these thresholds were developed as the flow was sweeping past the upstream seat retainer and leading edge of the ball element.
Despite the fact that the CFD model predicted that all characteristic elements for particle impact ignition could have been present at the time of the fire, WHA’s analysis of the burn patterns and post-fire evidence indicated that the most probable cause of this fire was contaminant promoted ignition. The CFD analysis provided key insight into each of these ignition mechanisms and also confirmed the relevant probable gas pressures and velocities inside the valve.
The first take away from this investigation is the importance of minimizing hydrocarbon-based contaminants in oxygen systems. Hydrocarbon contaminants require relatively little energy to ignite yet burn vigorously in oxygen with energies capable of propagating a fire to other materials (especially if gross quantities are present, as was the case in this valve).
A second lesson learned in this analysis is the importance of proper operation of isolation valves in oxygen. These valves are typically purposed only for isolating pressure and flow, not for throttling or controlling flow. As such they are generally to be operated fully open or fully closed, and not operated under pressure differentials which can produce very high gas velocity through the valve. A “zero pressure, zero flow” operating philosophy often applies to isolation valves in oxygen, where the valve is pre-positioned open before pressurized (zero pressure) or where pressure is equalized across the valve before opening (zero flow). If an isolation valve in an industrial oxygen system is not designed to be operated under pressure differentials (during system start-up or re-start for example), often a small-diameter bypass valve is used to slowly equalize pressure across that valve and enable safe operation.
WHA can address hazards in your systems before they develop into an incident. Contact us today to learn more about oxygen hazard analysis and technical training options available to optimize your systems and processes. We simplify oxygen safety so you can better protect your equipment, and most importantly, protect your personnel.Contact Us
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